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I don't know if Lex ever tried to romance Lois in the comic canon
A bunch of comics trivia... In the comics Lex was too old to romance Lois (he and Perry were around the same age and Lex was the natural father of Jerry White). But after Lex had cancer in 1993 he feign his death and went through a rejuvenation process, coming back as Lex Luthor Junior, supposed son of Lex Luthor and Dr. Gretchen Kelley raised in Australia (Leslie Luckabee, anyone?). During this time, he made a pass at Lois and she rejected him.

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Andreia

"My wife's love is what unites Krypton and Earth in my heart. Without it, without her, I truly would be in hell."

~ Superman: Man of Tomorrow #15