This is a completely random guess (I figure I have a 1 in 88 chance of being right!) but is it Meet John Doe? I can picture the scene but am not too sure about which episode!

Loriel

"Inappropriate attachment" didn't begin to cover the depth of the feelings Vaughn had for Sydney Bristow.
~Ties That Bind by RJ Anderson~

I ramble at http://www.livejournal.com/~loriel_eris